By Ernest W. Flick
This publication (Volume 2) provides numerous hundred complex cleansing product formulations for family, commercial and automobile purposes. All formulations are totally different from these in different volumes, so there's no repetition among volumes.
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Additional info for Advanced Cleaning Product Formulations, Volume 2
The energy change of step (2), DE2, depends linearly on DE1 owing to the thermodynamic constraint that 12DE1 þ DE2 ¼ DEr, where DEr is the overall energy change of the reaction. So far we have exclusively used the electronic ground-state energy, E, at T ¼ 0 K in all equations, which is the primary output of DFT calculations, but from thermodynamics we know that free energy changes are the correct quantities to use in the calculation of rate and equilibrium constants. We assume for now that the DFT-calculated electronic energy is approximately equal to the enthalpy and that the entropy change can be calculated separately.
How so? Well, a client (¼ reaction) who is seeking the help of a professional matchmaker (¼ us) in order to ﬁnd her/his perfect partner (¼ catalyst) will ﬁrst have to go through an in-depth interview. During the interview, the matchmaker thoroughly analyzes the client’s character/personal situation and describes it with certain adjectives (¼ descriptors), such as attractive (¼ aﬃnity to adsorbate ‘X’), ﬁnancially stable (¼ low cost material), emotionally stable (¼poisoning resistant), desire to get married (¼ long-term stability), and so on.
0. This leaves us with only the two unknown rate constants k1 and k2. We can obtain the rate constants, ki, from the standard Arrhenius expression, which depends on the activation energy, Ea,i, and the pre-exponential factor, ni, for each step. ÀEa;i ki ¼ ui Á exp ð1:32Þ kB T The pre-exponential factor ni can be calculated using transition state theory from the entropy change between the initial state and the transition state of the reaction, DSiz . kB T DSiz Á exp ui ¼ ð1:33Þ h kB Next, we obtain the activation barrier estimates from published scaling relations, beginning with N2 dissociation.
Advanced Cleaning Product Formulations, Volume 2 by Ernest W. Flick